I am trying to configure two PPP networks ( two Modems ) in single PC (Latest Redhat 3.10 kernel OS , I have tested on latest Ubuntu 18.04LTS). However, However everytime "While connecting two devices, Network Manager/Modem Manager is crashing."

Could you edit the title? it’s supposed to just a quick one-line summary!

I think its well-known that the Ubuntu modem manager crashes with the SiWi parts - so you need to disable it.

EDIT

etc…